Gamma Emission and Internal Conversion
The decay from an excited state in a nucleus to levels in the same nucleus can be achieved by a) gamma emission, and b) internal conversion. In the former, the excess energy is carried out by a photon, while in the latter, the excess energy is carried out by an orbiting electron.
The gamma energy is basically equal to the level energy difference (neglecting the recoil energy), while the electron energy is equal to the level energy difference minus the electron binding energy:
Eγ=Einitial level - Efinal level
Eelectron=Einitial level - Efinal level - Eelectron binding energy
The angular momentum and parity carried by a gamma ray is known as the multipolarity. The standard notation uses the letters M (magnetic) and E (electric) next to a number to indicate it:
The electron binding energy and the internal conversion probability depend on the orbit the electron occupied before the ejection. For instance, the atomic K orbit is the tightest bound, that is, it has the largest binding energy. It is also the one with the lowest value of angular momentum, which means it has the highest probability of finding the electron close to the nucleus, and as a result has the highest probability of conversion electron.
For each transition between levels, there is a gamma energy, Eγ, a gamma probability, Pγ, as well as an array of electron energies and probabilities Ei, Pi, where the index i indicates the atomic shell i. Each element of the array is tagged as "CE-i", for instance, "CE-K" means it is the conversion electron from the K-shell.
The total conversion coefficient, which is a function of the gamma multipolarity, is defined as:
α=Pinternal conversion / Pγ
and is equal to the sum of the individual conversion coefficients:
α=Σ αi / Pγ=Σ Pi / Pγ
Gamma emission and internal conversion are highly dependent on the angular momentum and parity differences between the initial and final levels. The larger the spin difference the less likely the probability per unit time (rate) of decay.
The majority of known nuclear levels have very short half-lives, smaller than 1 nano-second. The term "Isomeric Transition" (IT) is often used for gamma emission and electron conversion from a level with half-life larger than a given value, typically 1 nano-second.
For a gamma ray with energy Eγ, multipolarity Mλ/Eλ, conversion coefficient α, de-exciting a level with half-life T1/2, the partial half-life is given by:
Tγ=T1/2 / [Iγ(1+α)]
where Iγ is the gamma ray intensity normalized so that the sum of all intensities for the transitions de-exciting the same level is equal to one.
The reduced transition probability in Weisskopf units is defined as:
where TW is the Weisskopf single-particle estimate of the half-life. Its definition can be found in page iii of the Nuclear Data Sheets policies.