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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) September 25, 2009

Evidence for the formation of sodium hassate(VIII)

  • André von Zweidorf , W. Brüchle , S. Bürger , H. Hummrich , Jens Volker Kratz , B. Kuczewski , G. Langrock , U. Rieth , M. Schädel , N. Trautmann , K. Tsukada and N. Wiehl
From the journal Radiochimica Acta

Summary

Hassium, element 108, was produced in the fusion reaction between 26Mg and 248Cm. The hassium recoils were oxidized in-situ to a highly volatile oxide, presumably HsO4, and were transported in a mixture of He and O2 to a deposition and detection system. The latter consisted of 16 silicon PIN-photodiodes facing a layer of NaOH, which served, in the presence of a certain partial pressure of water in the transport gas, as reactive surface for the deposition of the volatile tetroxides. Six correlated α-decay chains of Hs were detected in the first 5 detectors centred around detection position 3. In analogy to OsO4, which forms Na2[OsO4(OH)2], an osmate(VIII), with aqueous NaOH, HsO4 presumably was deposited as Na2[HsO4(OH)2], a hassate(VIII).

Published Online: 2009-9-25
Published in Print: 2004-12-1

© 2004 Oldenbourg Wissenschaftsverlag GmbH

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