Elsevier

Chemical Physics Letters

Volume 203, Issues 2–3, 19 February 1993, Pages 243-247
Chemical Physics Letters

The relation betwen the 129Xe NMR chemical shifts of xenon in the zeolites NaX, NaY and CuNaY

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Abstract

The adsorption isotherms and 129Xe NMR chemical shifts of xenon in the voids of zeolite Y with 0%, 53%, 75%, and 95% exchange of copper (II) for sodium ions were determined. With increasing copper content the shifts go upfield. The local chemical shifts of xenon at a crystallographic SII site with and without the charge compensating sodium ion are condluced to be 60 and 32 ppm, respectively.

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